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News Source: World Science News
Date Released: February, 2008
Website: www.world-science.net
 
Sounds of Individual Molecules Captured
Courtesy of Courtesy Kansas State University and World Science staff
 














Part of a graphical depiction of the molecular vibrations. (Cour­tesy Max Planck Inst. for
Nuclear Physics)

Physicists say they’ve rec­orded ti­ny vibrations of in­di­vid­ual molecules, that could be called sounds—depending on how you de­fine sound—and put them in audible form.

The resulting bell-like tones can be heard here. But the study went much further.

The vibrations in their original form, scientists said, are too fast and small to hear, but otherwise fit the physical description of what makes a sound: they can produce similar vibrations in neighbo­ing molecules, which do the same to their neigh­bors, and so forth, spread­ing the oscillations outward.
That’s enough to meet some dictionary definitions of sound, though oth­ers apply the word only to what can be heard. Audi­ble sound consists of the same sorts of vibrations, but much bigger and slower, and affecting trillions of molecules, so they can move the eardrums.

Uwe Thumm, one of the researchers, said he prefers not to call the effects of a single molecule’s vibration “sound.” But “that’s a matter of what you define as ‘sound,’” he added. There’s no firm line between audible and inaudible: different animals are sensitive to very different vibration characteristics, though it’s safe to say none can hear a molecule.

Making a molecule’s vibrations audible, however, is just a matter of playing them back much, much slower and louder, researchers said.

To imagine what one molecule might sound like if you could hear it, picture the smallest bell you can: it would make a tiny, high-pitched ping. Now, try to conceive of a tone unimaginably smaller and higher. To convert this from a fantasy into something you can really hear would require doing what the researchers did: replaying a recording very slowly to lower the pitch—like a 45-rpm record being played at 33-rpm—and of course with a volume boost.

To make original the “sound” itself, Thumm, of Kansas State University, and colleagues struck hydrogen atoms with short, intense laser pulses. They then scaled the vibration speeds, or frequencies, down to about 1,000 Hertz, for a human-audible pitch.

But they went much further: they also analyzed the vibrations almost as music, to determine how the molecule, composed of mainly of two core particles called protons, reacted to the pulses. “The laser pulse either makes the molecules vibrate more violently or blows them apart,” Thumm said, which is unsurprising because protons are linked by smaller particles, electrons, that act as a spring. The protons, banged with a pulse, oscillate back and forth.

While this may be easy to picture on a large scale, Thumm said particles act differently at the subatomic, or quantum level. This means determining the protons’ locations after being hit isn’t easy.

It’s similar in a way to what happens if you drop a marble in a bath­tub, he said: looking at the circular ripples, one can at first tell where the marble was dropped. But when those ripples bounce off the tub’s sides, the wave pattern changes shape, and it becomes harder to tell where the marble fell. Thumm said the same thing happens to the protons not within seconds, but in about 60 billionths of a millionth of a second.

After this, you lose track of the distance between the protons, Thumm said. “All you can say is that they have a certain likelihood of being at a certain distance. This is in agreement with the bathtub experiment: Seconds after the marble was dropped, you can’t tell where exactly it plunged in.”

But things work still differently at the quantum level. The researchers said they were surprised to find that waiting about 10 times longer after the original hit, the proton-proton distance again becomes definite. “We call this a revival of the original motion,” Thumm said. “It’s not going to happen in the bathtub, but it happens at the quantum level.”

Thumm and colleagues analyzed molecular motions by breaking them into their various frequencies, or vibration speeds. Different frequencies are what create different pitches in music. The molecular frequencies could thus be analyzed as if they were musical chords.

This study—based on experiments at the Max Planck Institute for Nuclear Physics in Heidelberg, Germany—bore out the picture of “revival” of motion, Thumm said. And happily, he added, this also confirmed predictions he published in 2003 with the institute’s Bernold Feuerstein. The agreement “was almost perfect and exceeded our expectations,” Thumm said.

One can literally “listen to the vibrations and hear the ‘revival,’” Thumm said.

Thumm said researchers hope to be able to do the same thing for more complex molecules like water or methane. Just as a C Major chord sounds different from a D minor chord, Thumm said other molecules also would have their own un­ique sound. The study, published in the Oct. 10 issue of the research journal Physical Review Letters, could also help investigators in the goal of applying lasers to steer chemical reactions, Thumm said.
 

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This article first appeared in the World Science News on February 6, 2008. Their website can be found at www.world-science.net
 
 

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